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MOLECULAR WEIGHT DISTRIBUTION in NET Encode PDF-417 2d This autoacceleration sometimes occurs only after some polymer has formed, the formed polymer assisting in stabilizing the linear monomer aggregates (similar to template polymerization Carboxylic acid monomers such as acrylic and methacrylic acids and trans-butadiene-1carboxylic acid have lower polymerization rates in good solvents and/or at higher pH where monomer exists in ionized form Repulsions between the carboxylate anion groups of the propagating chain end and monomer result in lowered reactivity in the propagation step [Bando and Minoura, 1976; Ponratnam and Kapur, 1977] Monomers containing b-diketone and b-ketoester groups (eg, ethyl 4-methyl-3-oxo-4-pentenoate) exhibit higher reaction rates in benzene compared to acetonitrile The enol tautomer, more plentiful in the less polar solvent, is more reactive than the keto tautomer [Masuda et al, 1987, 1989].

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The addition of Lewis acids such as ZnCl2 and AlCl3 often increases the polymerization rate of monomers with electron-withdrawing substituents, such as acrylamide, methyl methacrylate, and acrylonitrile [Gromov et al, 1980a,b; Haeringer and Reiss, 1978; Kabanov, 1987; Liaw and Chung, 1983; Madruga and Sanroman, 1981; Maekawa et al, 1978; Sugiyama and Lee, 1977] The mechanism of acceleration is not well established In some instances the metal salt increases the initiation rate by complexing with the initiator Increased reactivity toward propagation by complexation of the propagating radical and/or monomer with the Lewis acid appears to be the predominant effect in other systems Simultaneous effects on both initiation and propagation (and possibly also termination) are indicated in many systems, since the polymer molecular weight often shows a maximum and a minimum with increasing concentration of Lewis acid.

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